x2 on what dc said
Valves are cut at a degree or 2 off from the seats so there should be a perfect line where they contact. Specs are in the book, no doubt.
If it was mine? x2 on atc500x too.
if it won't leak a small molecular weight solvent, it will prob run with no more concern.
If you are comfortable removing the valve springs, there is a blue dye you can use to see where the valves touch the seats and hopefully see a perfect sealing line. but again, if it doesn't leak, it'll prob run.
If the seats are

ed or buried, almost any machine shop can dress them up. If the guides are a little sloppy, they can be knurled instead or replaced sometimes. With the springs off, you can check for an axial side wobble.
If the carbon esthetics bother you, maybe some oven cleaner as long as it doesn't touch any rubber valve stem seals, if it has them.
ok, now why do you have a new head in the first place?