I don't know of any way to change them with the head still on. You would need to take the top cover off the head, which requires removing the 4 acorn nuts that hold the head to the jug, so air pressure could not be used to hold the valves in place like you do when changing valve springs and seals on car engines. Heads got to come off, but that's not a bad job. It takes longer to pull the engine out than to pull the head and put it back on. You may even be able to get the head off in the frame, not sure if there's enough room on that model.
1985 Tri-Z 250
1985 ATC250R