The rocker broke because when you "fixed" the timing you actually put it out of time. thus when you went to turn it over piston met valve and the rocker gave way.
I would count on a bent valve aswell.
Starter motors can power me on a KLT in gear up a steep hill there that powerfull(although not recommended).
Now this may sound slighty dumb but you sure your turning it over the right way?. If i were you instead of using the starter i would have put it in 4th gear and pushed it to bump start
At the relay there will be two BIG wires coming in from the battery and going to the starter. A way to test these would be to get a screwdriver and short the two terminals.
On the vavle clearences i would think you set them about right maybe too tight but that wouldnt screw the rocker.
Will
EDIT: another thing i do WHENEVER ive had an engine apart is spin it over 2 or 3 times by hand to check nothing is hitting and it spins freely
85 Tri-Z "Rumble Bee"
85 250R "Red Rocket"
83 200X "Flat Tracker"